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Seismic ground motion creates low-frequency atmospheric sound (infrasound) that is detectable at remote sensor arrays. However, earthquake infrasound signal analysis is complicated by interference between multiple waves arriving at sensors simultaneously, reducing the accuracy and detail of ground motion detection. Here we show that individual waves in complicated wavefields can be resolved by recording infrasound on large-N arrays and processing with CLEAN beamforming. Examining both a local (ML3.5, purely tropospheric infrasound propagation) and regional earthquake (ML6.5, upper-atmospheric returns), we detect infrasound from tens of km away and up to several hundred km away respectively. Source regions span arcs of approximately 90°, indicating that although detection bias does occur (most likely from atmospheric winds) the recorded infrasound sources are widely dispersed and not simply epicentral. Infrasound-based remote detection of ground motion over wide areas can complement point measurements by seismometers and spur innovations in earthquake research and real-time hazard monitoring.

 

This study quantified erosional and depositional processes for secondary lahars in Las Lajas drainage at Volcán de Fuego, Guatemala, during the rainy season from May to October 2021. Abundant pyroclastic material from ongoing eruptive activity is remobilized seasonally during heavy precipitation, which can impact infrastructure and populations living near Fuego. Our region of focus was in an agricultural zone 6 to 10 km from the summit, surveyed with an unoccupied aerial vehicle (UAV) quadcopter at monthly intervals. Imagery was processed into overlapping time-lapse structure from motion digital elevation models (DEMs). DEMs were differenced to find volumetric changes as a function of the channel flow path distance (quantified in 500 m sections) to track channel morphology changes over time. The largest measured volume changes were a 490 m3/day loss in the upper section (~6 km from summit) and a 440 m3/day gain in the lower sections (~10 km from summit). We discussed how the natural channel’s constriction and widening of Las Lajas in more distal sections control the behavior and stability of the stream evolution. Above the constriction, the channel is primarily downcutting and meandering within an old flood plain, which had been filled in by pyroclastic materials deposited by the June 2018 paroxysm. 

Atmospheric aerosol and chemistry modules are key elements in Earth system models (ESMs), as they predict air pollutant concentrations and properties that can impact human health, weather, and climate. The current uncertainty in climate projections is partly due to the inaccurate representation of aerosol direct and indirect forcing. Aerosol/chemistry parameterizations used within ESMs and other atmospheric models span large structural and parameter uncertainties that are difficult to assess independently of their host models. Moreover, there is a strong need for a standardized interface between aerosol/chemistry modules and the host model to facilitate portability of aerosol/chemistry parameterizations from one model to another, allowing not only a comparison between different parameterizations within the same modeling framework, but also quantifying the impact of different model frameworks on aerosol/chemistry predictions. To address this need, we have initiated a new community effort to coordinate the construction of a Generalized Aerosol/Chemistry Interface (GIANT) for use across weather and climate models. We aim to organize a series of community workshops and hackathons to design and build GIANT, which will serve as the interface between a range of aerosol/chemistry modules and the physics and dynamics components of atmospheric host models. GIANT will leverage ongoing efforts at the U.S. modeling centers focused on building next-generation ESMs and the international AeroCom initiative to implement this common aerosol/chemistry interface. GIANT will create transformative opportunities for scientists and students to conduct innovative research to better characterize structural and parametric uncertainties in aerosol/chemistry modules, and to develop a common set of aerosol/chemistry parameterizations.

 

Infrasound is increasing applied as a tool to investigate magma dynamics at active volcanoes, especially at open-vent volcanoes, such as Mt. Etna (Italy), which are prodigious sources of infrasound. Harmonic infrasound signals have been used to constrain crater dimensions and track the movement of magma within the shallow plumbing system. This study interprets the remarkable systematic change in monotonic infrasound signals preceding a lava fountaining episode at Mt. Etna on 20 February 2021. We model the changing tones (0.7 to 3 Hz fundamental frequency) as a rise in the magma column from 172 ± 25 m below the crater rim to 78 ± 8 m over the course of 24 h. The infrasonic gliding disappears approximately 4 h before the onset of lava fountaining as the magma column approaches the flare of the crater and acoustic resonance is no longer supported. The featured 20 February event was just one of 52 lava fountain episodes that occurred at Mt. Etna over the course of 9 months in 2021 and was the only lava fountain episode where dramatic gliding was observed as a subsequent partial collapse of the crater prevented future resonance. The results presented here demonstrate that analysis of infrasonic gliding can be used to track the position of the magma free surface and hence may provide information on the processes taking place within the plumbing system before eruptive activity.

 

(Diene)Rh(I) complexes catalyze the stereoselective three‐component coupling of silyl glyoxylates, arylboronic acids, and aldehydes to give glycolate aldol products. The participation of Rh‐alkoxides in the requisite Brook rearrangement was established through two component Rh‐catalyzed couplings of silyl glyoxylates with ArB(OH)₂to give silyl‐protected mandelate derivatives. The intermediacy of a chiral Rh‐enolate was inferred through enantioselective protonation using a chiral Rh‐catalyst. Diastereoselective three‐component couplings with aldehydes as terminating electrophiles to give racemic products were best achieved with a bulky aryl ester on the silyl glyoxylate reagent. Optimal enantioselective couplings were carried out with thetert‐butyl ester variant using an anisole‐derived enantiopure tricyclo[3.2.2.0^2,4]nonadiene ligand.

 

(Diene)Rh(I) complexes catalyze the stereoselective three‐component coupling of silyl glyoxylates, arylboronic acids, and aldehydes to give glycolate aldol products. The participation of Rh‐alkoxides in the requisite Brook rearrangement was established through two component Rh‐catalyzed couplings of silyl glyoxylates with ArB(OH)₂to give silyl‐protected mandelate derivatives. The intermediacy of a chiral Rh‐enolate was inferred through enantioselective protonation using a chiral Rh‐catalyst. Diastereoselective three‐component couplings with aldehydes as terminating electrophiles to give racemic products were best achieved with a bulky aryl ester on the silyl glyoxylate reagent. Optimal enantioselective couplings were carried out with thetert‐butyl ester variant using an anisole‐derived enantiopure tricyclo[3.2.2.0^2,4]nonadiene ligand.

 

Lahars are one of the greatest hazards at many volcanoes, including Volcán de Fuego (Guatemala). On 1 December 2018 at 8:00pm local Guatemala time (2:00:00 UTC), an hour-long lahar event was detected at Volcán de Fuego by two permanent seismo-acoustic stations along the Las Lajas channel on the southeast side. To establish the timing, duration, and speed of the lahar, infrasound array records were examined to identify both the source direction(s) and the correlated energy fluctuations at the two stations. Co-located seismic and acoustic signals were also examined, which indicated at least 5 distinct energy pulses within the lahar record.  We infer that varying sediment load and/or changes in flow velocity is shown by clear fluctuations in the acoustic and seismic power recorded at one of the stations. This particular event studied with infrasound provides insight into how lahars occur around Volcán de Fuego.